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If you liked R.O.D: The TV add

...then you might like Darker than Black: Kuro no Keiyakusha add

Both Darker than Black and R.O.D TV manage to blend supernatural themes/powers with a more or less realistic world really well. R.O.D is definitely more whimsical but still manages to balance the comedy moments with the serious action. Also both use an episodic structure arcing over the course of the season.