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While at first you may think these characters to be weird or you may even hate them, but throughout the story you realise they are not all they first appear to be... (I would give more details but I think you should check them out for yourselves as its more interesting that way)
1. SangWoo - Killing stalking (Manhwa)
2. Ukyo - Amnesia (there is an anime but I highly recommend the Visual novel)
3. Itachi Uchiha - Naruto (Anime/Manga)
4. Haru Yoshida - My Little Monster (there is an anime but it is bad and unfinished but the manga is one of my faves)
5. Kyo Souma - Fruits Basket (Anime/Manga)