Total Recommendations: 2
If you liked
Shinseiki Evangelion
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...then you might like
Bounen no Xamdou
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Psychological mecha anime's with main characters that begin to question their situation, both universes are at war with similar humanoid/robot enemies.
Anime rec by DriveYouCrazy - Apr 28, 2014
If you liked
Darker than Black: Kuro no Keiyakusha
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...then you might like
Fate/Zero
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Strong main male characters in Hei and Kiritsugu, both distant but powerful. 'Contractors' in Darker Than Black are the main source of supernatural power, whereas in Fate/Zero they come from a third party 'Servants'. Both have plots you can sink your teeth into and have a very similar feel to them, though differing plot.
Anime rec by DriveYouCrazy - Sep 26, 2013