 If you liked
World Teacher: Isekaishiki Kyouiku Agent
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 ...then you might like
Potion-danomi de Ikinobimasu!
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1) Both main character die and are reincarnated/transported into another orld
2) Both main character have very high skills comparison to other characters
3) Both main character are very wise and serious
4) Both main character are involved in economy and political themes
5) Both main character have the typical japanese appearance, and that is very strange in their new world