 If you liked
Kaichou wa Maid-sama!
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 ...then you might like
L♥DK
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The plot is not really the same(other than the high-school vibe), but the male and female lead are very similar. You've got a cool/teasing boy and a strong/indipendant girl. If you like one, you will definitelly love the other.
The story is similar, cause boy ( prince of the school ) in both manga is separate from all the girls ( of course, we don't know why - in the begining :) ) ; he's having fun with the girl he meet, but when he realise, he is already in love with her. The main female character is independent, and ... very shy.