 If you liked
Kaichou wa Maid-sama!
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 ...then you might like
Ookami-san to Shichinin no Nakama-tachi
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Both feature a hard-working tsundere as the main character. Male lead in Ōkami-san is not nearly as "cool" as Usui, but the relationship between the main characters is very similar in both. Both series are episodic and primarily humorous, with some drama. Art style is also very similar. Overall the two are very similar, but each has a distinct flavor that makes it well worth watching.