 If you liked
Hetalia Axis Powers
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 ...then you might like
Hataraku Saibou
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Both are "edutainment" anime that use humor to educate its audience on real concepts. Hetalia focuses on history while Hataraku Saibou discusses biology. Though Hetalia has an overarching WWII storyline and repeating gags, like Hataraku Saibou, Hetalia can be picked up at any episode due to its episodic formula.
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Recommended by Ultima_Oblivion
These two shows use anthropomorphism to illustrate an entity's "way of life". Hataraku Saibou illustrates the daily function of cells through human jobs and personalities. Hetalia illustrates the intermingled history of countries through its affinity or lack of affinity between characters as well as portraying their culture through habits and personality traits of their characters.
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Recommended by QuanekiQuen
Both shows humanize inanimate objects, in not only for humorous purposes but also to shed light on the real-life actions behind them (the human body in Cells at Work and the country relations during WWII in Hetalia)
Similarly, both shows consist of a large cast, yet focuses mostly on select few members
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Recommended by Short_Circut