 If you liked
Kaguya-sama wa Kokurasetai: Tensai-tachi no Renai Zunousen
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 ...then you might like
Rikei ga Koi ni Ochita no de Shoumei shitemita.
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Both shows have a similar vibe and atmosphere where the main characters which both happen to be in a sort of academic setting, try to prove that they are/aren't in love with each other in a comedic way for us viewing audience.
both are awkward but also hilarious in their situations.
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Recommended by kiichan123
-Both couples are in love with each other but refuse to express it.
-Both couples try to prove that they love each other through activities such as logical evidence or mind games.
-Romantic comedy
-Education setting (one in a high school, one in an university)
Both main couples of the anime try to define/understand their romantic feelings of each other. Rikekoi has a more scientific aspect to it in terms of "quantifying" their love whilst Kaguya-sama is a battle of wits to see who ends up confessing their feelings for each other.
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Recommended by Angel-uwu-
Our main characters both are in love with each other and over analyse the concept of love. Both good comedy series and share an education setting.
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Recommended by AmbiiBambi
They both have the same theme of a male & female couple that are obviously in love with each other, but both deny it. The main differing part is that in Kaguya Sama, they try to get each other to prove it, so it's like two tsunderes that are in love with each other, but in Rikei ga Koi ni Ochita no de Shoumei shitemita, they try and do wacky experiments (just activities normal couples do) to prove their love.
It involves two geniuses whom were in love with each other, but keeps beating around the bush........................................................................................TCH!
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Recommended by JiangHaoyi1979
Two geniuses have uncommon view of love that prevents them from actually starting to date.
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Recommended by blackhaulmike
Similarities:
- Two characters whom were part of the upper echelons of academics, but were the lowest of the low when it comes to romance.
-Two same characters whom has to go through a lot of wishy washy run around rather that just say it directly.
Dissimilarities:
-Both have the same deuteragonist characters whom were with the two protagonist, but in one anime the deuteragonist there was just as useless as the two protagonists there. While in one anime the deuteragonists there were pretty useful, but the two protagonists were a duo of thick skulled morons.
-The settings were different where one was in a school
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Recommended by Horn_dawg_2019
In Kaguya two tsundere try to get each other to confess.
In rikei two scientists try to prove they are/aren't in love.
Both shows have a similar atmosphere and the characters in each show are to an extent a perfect copy of one another
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Recommended by QuickSilver7259
Kind of the same
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Recommended by Yan-AnsonI
Like Kaguya-sama, the characters of Science Fell in Love are hopeless romantics who find themselves in the most ridiculous situations trying to get into a relationship. With fun, lovable side characters alongside them, they have the unique chemistry that only two scientific geniuses experiencing love for the first time can have. Science Fell in Love is a perfect follow-up for fans of Kaguya-sama. It is set in college, unlike Kaguya-sama, but the mood throughout the show remains the same.
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Recommended by Ragerrodent
Both anime are about 2 people who refuse to acknowledge that they love one another. It is obvious to everyone else who watches that they do love each other. They are both really cute couples and are excellent rom-com anime.
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Recommended by mluhmluhmluh
Both have two characters who are in love, but do not want to expose their feelings. Also, in each ep some different "adventure" happens similar to love is war.
Both shows have innocent couples that are trying to navigate love for the first time. Both couples are over the top, clueless, and hilarious.
These series wherein love is explored in unique way but comes up with comedic struggles. Both the main characters from them uses intelligence as their tactic to explore something to discover and prove the romantic feelings from each other.
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Recommended by kageyama_shigeo
RomCom. Main characters have interests for another but doesn't believe its true? So they tried their best to find out the truth.
I own all mangas (#23 for Kaguya and #10 for Rikekoi) for both series. Both shows have smart main characters who are good at everything except for romance. Both shows feature characters making baby steps (and tons of mistakes) while they try to get together. Kaguya has more dark moments (and more depth to the characters and story) while Rikekoi is composed almost entirely of happy lovey-dovey scenes. In other words, I feel that Rikekoi is the less dramatic, easier-to-consume cousin to Kaguya, but both shows are equally awesome.