 If you liked
Shakugan no Shana
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 ...then you might like
Kyuuketsuhime Miyu (TV)
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They are both anti-heroines who are trying to, not save Earth, but make sure evil beings don't harm humans. They both were sent to Earth on a mission with fire as their element. Despite having no feelings for humans, they both befriend some and disguise themselves as school girls. There is also a dark motif where humans die, and Shana and Miyu don't feel any sorrow for their death. Also, they have a male compainion who helps them.
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Recommended by mistress_reebi