 If you liked
Samurai Champloo
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 ...then you might like
Darker than Black: Kuro no Keiyakusha
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Darker than Black has a similar episodic style to Samurai Champloo. Also similar to Samurai Champloo, Darker than Black has a core group of characters whose histories and motives are gradually revealed as the plot progresses, along a bevy of interesting minor characters.