If you liked
Aoki Hagane no Arpeggio: Ars Nova
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...then you might like
Darling in the FranXX
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While not technically a mecha show, Arpeggio of Blue Steel has a similar sort of premise to Darling in the FranXX. A short and sweet story, Arpeggio is about a futuristic world in which climate change has isolated mankind. A mysterious navy of anthropomorphic avatars keeps mankind blockaded from the seas. Only one of these anthropomorphic ships sides with humanity, giving them a chance to fight back and be free. Obviously there is some parallel here to Zero-Two, who being half Klaxosaur gives humanity a chance in there own similar plight in Darling.
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