 If you liked
Kakumeiki Valvrave
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 ...then you might like
Aldnoah.Zero
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These two anime bring together mecha, space opera and domestic highschool life.
In ALDNOAH.ZERO, the Earth is attacked by Vers who are Martian colonists. Students on Earth learn to pilot mecha called Kataphrakts as part of their curriculum, it is only when their city is being destroyed by the Vers that they voluntarily take up the duty to defend themselves using the mecha they train with at school. The heroes of the show are led by pilot and tactical genius Inaho Kaizuka, the protagonist, and his bitter rival who fights for Vers is Slaine Troyard, who has a close friendship with Versian princess Asseylum. From then
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Recommended by Fortress_Maximus
These are both great mecha animes that i enjoyed. They both focus on good mecha fights and great character development with similar characteristics shared between characters.
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Recommended by AsianMafia
Both anime are mecha wars in witch most of MCs are from highscholl, both anime are showing perspective of both sides, in both anime one side has far stronger military power, both Anime are happening in a far future, both anime concentrate a lot on military tactics in battles, both anime have drama in it too, they give you a very similar feelings while watching them and they have many other smaller similarities.
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Recommended by YamiNoOkami
The genres are similar with school and mecha. The characters are also really alike, with the protagonist 'saving the day' with his grey haired enemy.
Pretty similar, but the students in Aldnoah are trained for the mech fights while in Valvrave, it was pretty unexpected. The princess in Valvrave does not have a main role and she is only in a few of the episodes. Plus, there is some vampire stuff in Valvrave, but Martian stuff in Aldnoah.
The two main character personalities are flipped, but they have the same roles
Both have a love interest in the princess and betrayed their side (the antagonist side): L-Elf--> Slaine
Both are pretty normal main characters (not counting Haruto's situation) who have a talent with piloting the mechs: Haruto --> Inaho
Personality Wise
Pretty emotionless and
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Both Mecha shows about an Outer Space Empire/Federation trying to take over parts of the Earth. (JIOR as in Kakumeiki Valvrave, a neutral and republic state based in space.)
Both the antagonists, L-Elf Karlstein(Kakumeiki Valvrave) and Slaine Troyard(Aldnoah.Zero) share some similar resemblances. Both are smart, elegant and cool-headed.
The only dissimilarity in both is that the protagonist and antagonist from Kakumeiki Valvrave get along as buddies as the show progresses, which is the opposite in Aldnoah.Zero.
P.S. Please take note that this recommendation is valid to the 2nd seasons of Kakumeiki Valvrave and Aldnoah.Zero respectively as well.
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Recommended by karlstein12
These are both mecha and there are some space battles in both shows. Mechas in both shows have some kind of supernatural looking tech.
Both of these shows end first season on cliffhanger. They show promise that's mostly wasted and ruined by bad writing.
There is clever/powerful character in both shows, although Valvrave's character acts like human at some points while A.Z's is more like emotionless overpowered husk.
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Recommended by opasnimiki
Showing mecha with both shounen as the main cast.
Fight over the great powers of "aldnoah" and "runes" to control mecha robots.
Military space battles where to defend the life of the earth.
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Recommended by ivialvamart
Beautiful artstyles
The main heros look similar (though the conflict is not that similar and the characters are, other than looking similar, pretty different in these anime)
Both are mecha anime
Both of them are pretty sad and dramatic
Setting in space, fractions that fight each other
Protagonists are the same age
Awesome fights
Same plot
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Recommended by PrettySenpai_
Both shows have two big forces fighing each other with big mecha robots. The story is somewhat similar and if you liked one of those, you will probably like the other.
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Recommended by europepact